Recently I've seen question regarding on which interface in LTE or UMTS the DIAMETER protocol is used.
Basically DIAMETER is an Authentication, Authorization & Accounting (AAA) protocol. That is why any of you will see DIAMETER used for these functions.
S6a - Authentication, more in TS 29.272
Gy - Prepaid charging, more in TS 23.203, TS 32.299;
Gz - Postpaid charging;
Gx - QoS/Policy, more in TS 29.211, TS 29.212;
Rf - Charging, more in TS 32.299;
Ro - Charging, more in TS 32.299;
Rx - QoS/Policy, more in TS 29.214;
S6d - Authentication;
S9 - QoS/Policy;
Sh - Subscriber Profile;
Cx - Subscriber Profile;
e2 - Location.
But also few others specific to IMS